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which is the order expected on the basis of the electron-donating ability of the various substituents. Monomers with electron-withdrawing substituents such as acrylonitrile, methyl methacrylate, and vinyl chloride show negligible reactivity in cationic copolymerization. There has been some success in correlating log 1=r1 with the e values from the Q e scheme [Ham, 1977]. Steric effects similar to those in radical copolymerization are also operative in cationic copolymerizations. Table 6-9 shows the effect of methyl substituents in the a- and bpositions of styrene. Reactivity is increased by the a-methyl substituent because of its electrondonating power. The decreased reactivity of b-methylstyrene relative to styrene indicates that the steric effect of the b-substituent outweighs its polar effect of increasing the electron density on the double bond. Furthermore, the trans-b-methylstyrene appears to be more reactive than the cis isomer, although the difference is much less than in radical copolymerization (Sec. 6-3b-2). It is worth noting that 1,2-disubstituted alkenes have nite r values in cationic copolymerization compared to the values of zero in radical copolymerization (Table 6-2). There is a tendency for 1,2-disubstituted alkenes to self-propagate in cationic copolymerization, although this tendency is low in the radical reaction. how to print pdf file without preview using java Generating thumbnail of a pdf using PDF.js - Stack Overflow
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Dec 6, 2016 · Mozilla's PDF.JS is PDF viewer made with HTML5 technologies. It can help your application in custom rendering of PDF files — showing a PDF ... It has previously been shown that large changes can occur in the rate of a cationic polymerization by using a different solvent and/or different counterion (Sec. 5-2f). The monomer reactivity ratios are also affected by changes in the solvent or counterion. The effects are often complex and dif cult to predict since changes in solvent or counterion often result in alterations in the relative amounts of the different types of propagating centers (free ion, ion pair, covalent), each of which may be differently affected by solvent. As many systems do not show an effect as do show an effect of solvent or counterion on r values [Kennedy and Marechal, 1983]. The dramatic effect that solvents can have on monomer reactivity ratios is illustrated by the data in Table 6 10 for isobutylene-p-chlorostyrene. The aluminum bromide-initiated copolymerization shows r1 1:01, r2 1:02 in n-hexane but how to print pdf file without preview using java Javascript - Previewing PDFs During Upload
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Aug 29, 2013 · (for example in a subdirectory called / Viewer.js ) put some ODF ... ViewerJS must be the easiest way to use presentations, spreadsheets, PDF's ... If thou lend money to any of my people that is poor by thee, thou shalt not be to him as an usurer. Exodus 22:25 Thou shalt not lend upon usury to thy brother; usury of money; usury of victuals; usury of anything. . . . Unto a stranger thou mayest lend upon usury; but unto thy brother thou shalt not lend upon usury. . . . Deuteronomy 23:19 20 He that hath not given forth upon usury, neither hath taken any increase . . . he is just, he shall surely live, saith the Lord God. Ezekiel 18:8 . . . lend freely, hoping nothing thereby. Luke 6:35 TABLE 6-10 Effect of Solvent and Initiator on r Values in Cationic Copolymerization r1 Isobutylene 1.01 14.7 8.6 Solvent n-C6H14 (E 1.8) f-NO2 (E 36) f-NO2 (E 36) r1 14:7, r2 0:15 in nitrobenzene The variation in r values has been attributed to the preferential solvation of propagating centers in the nonpolar medium (n-hexane) by the more polar monomer (p-chlorostyrene) The increased local concentration of p-chlorostyrene at the reaction site results in its greater incorporation into the copolymer than expected, based on the composition of the comonomer feed in the bulk solution Calculation of r values using the bulk comonomer feed composition results in a lower value of r1 coupled with a higher value of r2 In the polar nitrobenzene the propagating centers are completely solvated by the solvent without participation by p-chlorostyrene, and the more reactive isobutylene exhibits its greater reactivity The effect of solvent on monomer reactivity ratios cannot be considered independent of the counterion employed. Accordingly all the saints and all the angels of paradise cry then against [the usurer], saying, To hell, to hell, to hell. Also the heavens with their stars cry out, saying, To the fire, to the fire, to the fire. The planets also clamor, To the depths, to the depths, to the depths. ST. BERNARDINE, De Contractibus, Sermon 45, art. 3: c. 3 Upon the outermost Head of that seventh circle . . . Where sat the melancholy folk (the usurers) Out of their eyes was gushing forth their woe. DANTE, Divine Comedy, Inferno: Canto VII Dry pigments in powdered form are available from art supply outlets. These are available in all colors in both flat and metallic varieties. I keep a variety on hand for various art projects. Again, the situation is dif cult to predict with some comonomer systems showing altered r values for different initiators and others showing no effects Thus the isobutylene p-chlorostyrene system (Table 6 10) shows different r1 and r2 for AlBr3 and SnCl4 The interdependence of the effects of solvent and counterion are shown in Table 6 11 for the copolymerization of styrene and p-methylstyrene The initiators are listed in order of their strength as measured by their effectiveness in homopolymerization studies Antimony pentachloride is the strongest initiator and iodine the weakest The order is that based on the relative concentrations of different types of propagating centers The data in Table 6 11 show the copolymer composition to be insensitive to the initiator for solvents of high polarity (1,2-dichloroethane and nitrobenzene) and also insensitive to solvent polarity for any initiator except the strongest (SbCl5). how to print pdf file without preview using java Custom PDF Rendering in JavaScript with Mozilla's PDF.Js - SitePoint
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